Construction of dual heterogeneous interface between zigzag-like Mo-MXene nanofibers and small CoNi@NC nanoparticles for electromagnetic wave absorption

Two-dimensional (2D) transition metal carbides (MXene) process attractive conductivity and abundant surface functional groups, providing immense potential in the field of electromagnetic wave (EMW) absorption. However, high spontaneous aggregation MXene suffer from limited EMW response. Inspired by dielectric-magnetic synergy effect, strategy decorating with magnetic elements is expected to solve this challenge. In work, zigzag-like Mo2TiC2 nanofiber (Mo-MXene NFs) cross-linked networks are fabricated using HF etching KOH shearing processes. Subsequently, Co-MOF derived CoNi LDH ultrathin nanosheets grown inside Mo-MXene NFs, N-doped carbon matrix anchored alloy nanoparticles formed pyrolysis firmly embedded NFs network. Benefiting synergistic effect highly dispersed small nanoparticles, a 3D conductive network assembled numerous hollow vesicles, dual heterogeneous interface, designed Mo-MXene/CoNi-NC heterostructure provides robust absorption ability reflection loss (RL) value -68.45 dB at matching thickness 4.38 mm. The performance can be attributed excellent dielectric losses, loss, impedance matching, multiple scattering triggered unique structure. This work puts up great developing advanced MXene-based devices.